The Timaeus is the dialogue that was for many centuries the most influential of Plato’s works. Among its readers we find Descartes, Boyle, Kepler and Heisenberg. In the first division of Timaeus Plato deals with the theory of celestial motion, in the second he presents us with the first mathematical theory of the structure of matter. Here, in a gigantic step forward with respect to the preceding Democritean atomistic theory with its unalterable micro-entities, he introduces the intertransformability of elementary corpuscles (...) and with that the first “chemical” reactions in history. Plato’s geometrical interpretation of Empedocles’ elements and his geometrical atomism is described at the molecular, atomic and sub-atomic level. The “chemical” reactions reported in Timaeus are written in the enlightening chemical symbolism, analogies with modern chemistry are noticed throughout. (shrink)

Examples are given of applications by Pauling, Mulliken, Marcus and G.E.Kimball of the three Pythagorian means to formulate the scales of electronegativity of the elements, to the calculations of rate constants of electron transfer cross-reactions, to the calculation of the observed rate constant as function of activation and diffusion rate constants in the case of mixed reaction-diffusion rates and to the calculation of the effective diffusion coefficient in solution of a salt AB as a whole from the diffusion coefficients of (...) the ions in which it dissociates. (shrink)

Professor Rudolph A. Marcus, recipient of the 1992 Nobel Prize in Chemistry, is a distinguished theoretical chemist. Two important theories happen to bear his name: the Rice Ramsperger Kassel Marcus theory of unimolecular reactions and the Marcus theory of electron transfer reactions. When considering Marcus’ work, one finds characteristics of it that bear striking similarity to those that can be found in the work of some famous scientists. Such characteristics appear then as common recurring patterns in the work of theoreticians. (...) Among them we find the following: the creation of new theories, driven by experiments that preceding theories were unable to explain; the use of thought experiments; the generalization and extensions from one realm of science to another; the making of predictions and the finding of new properties from correlations among series of data; the use of variational principles; the providing of different demonstrations of an equation; the introduction of new types of coordinates; the innovative capacity to use, by somehow recreating it under the pressure of the physical problem, a mathematical method previously unknown to the author; and finally, the presentation of formulations of the same theory in different mathematical and physical languages. Before discussing in some detail the above points, a brief description of Marcus’ work is first presented for the convenience of the reader. (shrink)